mucciak9654 mucciak9654
  • 14-01-2020
  • Chemistry
contestada

Apply the Henderson-Hasselbalch equation to calculate the CH3NH3'/ CH3NH2 ratio in water buffered at PH 7.

Respuesta :

Mergus Mergus
  • 15-01-2020

Answer:

[tex]\frac{[CH_3NH_3^+]}{[CH_3NH_2]}=4168.69[/tex]

Explanation:

As we know that:-

For [tex]CH_3NH_2[/tex]:-

[tex]pK_{b}=3.38[/tex]

pH = 7

Also, pH + pOH = 14  

So, pOH = 14 - 7 = 7

Considering the Henderson- Hasselbalch equation for the calculation of the pOH of the basic buffer solution as:

[tex] pOH=pK_b+log\frac{[CH_3NH_3^+]}{[CH_3NH_2]} [/tex]

So,  

[tex] 7=3.38+log\frac{[CH_3NH_3^+]}{[CH_3NH_2]}  [/tex]

[tex]log\frac{[CH_3NH_3^+]}{[CH_3NH_2]} = 7-3.38=3.62[/tex]

[tex]\frac{[CH_3NH_3^+]}{[CH_3NH_2]}=4168.69[/tex]

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