Identify which sets of quantum numbers are valid for an electron. Each set is ordered ( n,ℓ,mℓ,ms ).

2,1,1,1/2
3,1,-1,1/2
3,2,-1,-1/2
4,2,1,1/2
4,3,-4,1/2
2,-1,1,-1/2
0,2,0,1/2
3,2,1,-1
1,0,0,-1/2
2,2,1,1/2
3,3,-2,-1/2
2,2,1,-1/2